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Issue 16, 2010
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Switching slow relaxation in a MnIII3MnIV cluster: an example of grafting single-molecule magnets onto polyoxometalates

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Abstract

Binding an established single-molecule magnet cluster of distorted cubane type [MnIII3MnIVO4] to the lacunary site of an {α-P2W15} polyoxotungstate scaffold results in a surprising zero-field splitting inversion and the subsequent loss of magnetization bistability.

Graphical abstract: Switching slow relaxation in a MnIII3MnIV cluster: an example of grafting single-molecule magnets onto polyoxometalates

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Publication details

The article was received on 10 Dec 2009, accepted on 03 Feb 2010 and first published on 25 Feb 2010


Article type: Communication
DOI: 10.1039/B925947C
Citation: Chem. Commun., 2010,46, 2760-2762
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    Switching slow relaxation in a MnIII3MnIV cluster: an example of grafting single-molecule magnets onto polyoxometalates

    X. Fang, M. Speldrich, H. Schilder, R. Cao, K. P. O'Halloran, C. L. Hill and P. Kögerler, Chem. Commun., 2010, 46, 2760
    DOI: 10.1039/B925947C

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