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Issue 12, 2010
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A square-planar Ni(II) complex with an N2S2 donor set similar to the active centre of nickel-containing superoxide dismutase and its reaction with superoxide

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Abstract

The structure around the metal centre of a Ni(II) complex with an N2S2 square-planar geometry, 1, prepared as a model compound of the NiSOD active site was drastically changed upon addition of potassium superoxide (KO2).

Graphical abstract: A square-planar Ni(ii) complex with an N2S2 donor set similar to the active centre of nickel-containing superoxide dismutase and its reaction with superoxide

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Publication details

The article was received on 08 Dec 2009, accepted on 28 Jan 2010 and first published on 12 Feb 2010


Article type: Communication
DOI: 10.1039/B925755A
Citation: Chem. Commun., 2010,46, 2142-2144
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    A square-planar Ni(II) complex with an N2S2 donor set similar to the active centre of nickel-containing superoxide dismutase and its reaction with superoxide

    D. Nakane, S. Kuwasako, M. Tsuge, M. Kubo, Y. Funahashi, T. Ozawa, T. Ogura and H. Masuda, Chem. Commun., 2010, 46, 2142
    DOI: 10.1039/B925755A

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