A square-planar Ni(II) complex with an N2S2 donor set similar to the active centre of nickel-containing superoxide dismutase and its reaction with superoxide

Daisuke Nakane; Shin-ich Kuwasako; Michiharu Tsuge; Minoru Kubo; Yasuhiro Funahashi; Tomohiro Ozawa; Takashi Ogura; Hideki Masuda

doi:10.1039/B925755A

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A square-planar Ni(ii) complex with an N₂S₂ donor set similar to the active centre of nickel-containing superoxide dismutase and its reaction with superoxide†

Daisuke Nakane,^a Shin-ich Kuwasako,^a Michiharu Tsuge,^a Minoru Kubo,^b Yasuhiro Funahashi,^a Tomohiro Ozawa,^a Takashi Ogura^b and Hideki Masuda*^a

Author affiliations

* Corresponding authors

^a Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan
E-mail: masuda.hideki@nitech.ac.jp

^b Graduate School of Life Science, University of Hyogo, 3-2-1 Kouto, Kamigori-cho, Ako-gun, Hyougo 678-1297, Japan

Abstract

The structure around the metal centre of a Ni(II) complex with an N₂S₂ square-planar geometry, 1, prepared as a model compound of the NiSOD active site was drastically changed upon addition of potassium superoxide (KO₂).

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Article information

DOI: https://doi.org/10.1039/B925755A
Article type: Communication
Submitted: 08 Dec 2009
Accepted: 28 Jan 2010
First published: 12 Feb 2010

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Chem. Commun., 2010,46, 2142-2144

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A square-planar Ni(II) complex with an N₂S₂ donor set similar to the active centre of nickel-containing superoxide dismutase and its reaction with superoxide

D. Nakane, S. Kuwasako, M. Tsuge, M. Kubo, Y. Funahashi, T. Ozawa, T. Ogura and H. Masuda, Chem. Commun., 2010, 46, 2142 DOI: 10.1039/B925755A

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