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Issue 17, 2010
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Single-ion magnets based on mononuclear lanthanide complexes with chiral Schiff base ligands [Ln(FTA)3L] (Ln = Sm, Eu, Gd, Tb and Dy)

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Abstract

A series of mononuclear lanthanide complexes with chiral Schiff base ligands [Ln(FTA)3L] [Ln = Dy(1), Sm(2), Eu(3), Gd(4), and Tb(5), L = (S,S)-2,2′-Bis(4-benzyl-2-oxazoline)] were synthesized and characterized. Among these complexes, complex 1 represents the first example of mononuclear lanthanide complexes displaying single-ion magnet behavior and ferroelectricity.

Graphical abstract: Single-ion magnets based on mononuclear lanthanide complexes with chiral Schiff base ligands [Ln(FTA)3L] (Ln = Sm, Eu, Gd, Tb and Dy)

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Publication details

The article was received on 24 Nov 2009, accepted on 02 Mar 2010 and first published on 24 Mar 2010


Article type: Communication
DOI: 10.1039/B924547B
Citation: Chem. Commun., 2010,46, 2929-2931
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    Single-ion magnets based on mononuclear lanthanide complexes with chiral Schiff base ligands [Ln(FTA)3L] (Ln = Sm, Eu, Gd, Tb and Dy)

    D. Li, T. Wang, C. Li, D. Liu, Y. Li and X. You, Chem. Commun., 2010, 46, 2929
    DOI: 10.1039/B924547B

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