Pressure-induced Jahn–Teller switching in a Mn12 nanomagnet

Pascal Parois; Stephen A. Moggach; Javier Sanchez-Benitez; Konstantin V. Kamenev; Alistair R. Lennie; John E. Warren; Euan K. Brechin; Simon Parsons; Mark Murrie

doi:10.1039/B923962F

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Chemical Communications

Issue 11, 2010

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Pressure-induced Jahn–Teller switching in a Mn₁₂ nanomagnet

Pascal Parois , Stephen A. Moggach , Javier Sanchez-Benitez , Konstantin V. Kamenev , Alistair R. Lennie , John E. Warren , Euan K. Brechin , Simon Parsons and Mark Murrie

Chem. Commun., 2010,46, 1881-1883

DOI: 10.1039/B923962F
Received 16 Nov 2009, Accepted 21 Dec 2009
First published on the web 18 Jan 2010

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Pressure-induced switching of a fast-relaxing single-molecule magnet to a slow-relaxing isomer is observed for the first time by using a combination of high pressure single-crystal X-ray diffraction and high pressure magnetic measurements.