Issue 15, 2010
From the journal:

Chemical Communications

Axial ligand control over monolayer and bilayer formation of metal-salophens at the liquid–solid interface†‡

Johannes A. A. W. Elemans,*a   Sander J. Wezenberg,b   Michiel J. J. Coenen,c   Eduardo C. Escudero-Adán,b   Jordi Benet-Buchholz,b   Duncan den Boer,c   Sylvia Speller,c   Arjan W. Kleij*bd  and  Steven De Feyter*a  

* Corresponding authors

a Department of Chemistry, Division of Molecular and Nano Materials, and INPAC – Institute for Nanoscale Physics and Chemistry, Katholieke Universiteit Leuven, Celestijnenlaan 200-F, 3001 Leuven, Belgium
E-mail: J.Elemans@science.ru.nl, steven.defeyter@chem.kuleuven.be

b Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain
E-mail: akleij@iciq.es

c Institute for Molecules and Materials, Radboud University Nijmegen, Heyendaalseweg 135, 6525 AJ Nijmegen, The Netherlands

d Institució Catalana de Recerca i Estudis Avançats (ICREA), Pg. Lluís Companys 23, 08010 Barcelona, Spain

Abstract

Nickel salophens exclusively form monolayers at a liquid–solid interface, while in contrast zinc salophens mainly self-assemble into bilayers via axial ligand self-coordination which can be disrupted by the addition of pyridine axial ligands.

Graphical abstract: Axial ligand control over monolayer and bilayer formation of metal-salophens at the liquid–solid interface

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Article information

DOI
https://doi.org/10.1039/B922212J
Article type
Communication
Submitted
23 Oct 2009
Accepted
07 Jan 2010
First published
25 Jan 2010

Chem. Commun., 2010,46, 2548-2550

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Axial ligand control over monolayer and bilayer formation of metal-salophens at the liquid–solid interface

J. A. A. W. Elemans, S. J. Wezenberg, M. J. J. Coenen, E. C. Escudero-Adán, J. Benet-Buchholz, D. den Boer, S. Speller, A. W. Kleij and S. De Feyter, Chem. Commun., 2010, 46, 2548 DOI: 10.1039/B922212J

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