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Issue 9, 2010
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Facile access to internally functionalized dendrimers through efficient and orthogonal click reactions

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Abstract

A simple synthetic strategy has been developed for accessing internally functionalized dendrimers. The key feature of this approach is the use of two orthogonal and efficient reactions—‘epoxy–amine’ and ‘thiolene’ coupling—for rapid growth of the dendritic scaffold. This sequence of reactions allows for the introduction of reactive hydroxyl groups at each dendritic layer.

Graphical abstract: Facile access to internally functionalized dendrimers through efficient and orthogonal click reactions

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Publication details

The article was received on 15 Oct 2009, accepted on 14 Jan 2010 and first published on 28 Jan 2010


Article type: Communication
DOI: 10.1039/B921598K
Citation: Chem. Commun., 2010,46, 1556-1558
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    Facile access to internally functionalized dendrimers through efficient and orthogonal click reactions

    T. Kang, R. J. Amir, A. Khan, K. Ohshimizu, J. N. Hunt, K. Sivanandan, M. I. Montañez, M. Malkoch, M. Ueda and C. J. Hawker, Chem. Commun., 2010, 46, 1556
    DOI: 10.1039/B921598K

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