Single and double substrate insertion into the TiNα bonds of terminal titanium hydrazides

Pei-Jen Tiong; A. Daniel Schofield; Jonathan D. Selby; Ainara Nova; Eric Clot; Philip Mountford

doi:10.1039/B920090H

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Chemical Communications

Issue 1, 2010

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Single and double substrate insertion into the TiN_α bonds of terminal titanium hydrazides

Pei-Jen Tiong , A. Daniel Schofield , Jonathan D. Selby , Ainara Nova , Eric Clot and Philip Mountford

Chem. Commun., 2010, 46, 85-87

DOI: 10.1039/B920090H
Received 28 Sep 2009, Accepted 02 Nov 2009
First published on the web 19 Nov 2009

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Abstract
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Nitriles, CO₂ and isocyanates undergo net single or double insertion reactions into the Ti [double bond, length as m-dash] N_α multiple bonds of terminal titanium hydrazides. These are the first such examples of this type of reactivity for any transition metal hydrazide complex.

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Pei-Jen Tiong
A. Daniel Schofield
Jonathan D. Selby
Ainara Nova
Eric Clot
Philip Mountford

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Chemical Communications

Single and double substrate insertion into the TiN_α bonds of terminal titanium hydrazides

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