Bis(oxazolinyl)phenyl transition-metal complexes: asymmetric catalysis and some reactions of the metals

Hisao Nishiyama; Jun-ichi Ito

doi:10.1039/B918923H

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Chemical Communications

Issue 2, 2010

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Bis(oxazolinyl)phenyl transition-metal complexes: asymmetric catalysis and some reactions of the metals

Hisao Nishiyama and Jun-ichi Ito

Chem. Commun., 2010, 46, 203-212

DOI: 10.1039/B918923H
Received 11 Sep 2009, Accepted 26 Oct 2009
First published on the web 19 Nov 2009

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Several transition-metal complexes that bind the bis(oxazolinyl)phenyl moiety as a tridentate ligand have been prepared to showcase their highly potent activities for asymmetric catalysis in conjugate reductions, reductive aldol reactions, direct aldol reactions and hydrogenation reactions. Some reactions of the metals were also examined.

Abstract from Methods in Organic Synthesis 2010

A review, with 51 references, of the use of the bis(oxazolinyl)phenyl moiety as a tridentate ligand for transition metals, and their use in the asymmetric catalysis of conjugate reductions, reductive aldol reactions, direct aldol reactions and hydrogenation reactions.

Abstract from Catalysts & Catalysed Reactions 2010

A review, with 51 references, describing the preparation of transition metal catalysts and their use in direct aldol reactions, reductive aldol reactions, hydrogenation reactions and conjugate reductions.

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Chemical Communications

Bis(oxazolinyl)phenyl transition-metal complexes: asymmetric catalysis and some reactions of the metals

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