A seven atom cluster in a carbon cage, the crystallographically determined structure of Sc4(μ3-O)3@Ih-C80

Brandon Q. Mercado; Marilyn M. Olmstead; Christine M. Beavers; Michael L. Easterling; Steven Stevenson; Mary A. Mackey; Curtis E. Coumbe; Joshua D. Phillips; J. Paige Phillips; Josep M. Poblet; Alan L. Balch

doi:10.1039/B918731F

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Chemical Communications

Issue 2, 2010

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A seven atom cluster in a carbon cage, the crystallographically determined structure of Sc₄(μ₃-O)₃@I_h-C₈₀

Brandon Q. Mercado , Marilyn M. Olmstead , Christine M. Beavers , Michael L. Easterling , Steven Stevenson , Mary A. Mackey , Curtis E. Coumbe , Joshua D. Phillips , J. Paige Phillips , Josep M. Poblet and Alan L. Balch

Chem. Commun., 2010, 46, 279-281

DOI: 10.1039/B918731F
Received 09 Sep 2009, Accepted 27 Oct 2009
First published on the web 09 Nov 2009

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The tetrahedral array of four scandium atoms with oxygen atoms capping three of the four faces found in Sc₄(μ₃-O)₃@I_h-C₈₀ is the largest cluster isolated to date inside a fullerene cage.

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Chemical Communications

A seven atom cluster in a carbon cage, the crystallographically determined structure of Sc₄(μ₃-O)₃@I_h-C₈₀

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