Thioether S-ligation in a side-on μ-η2:η2-peroxodicopper(II) complex

Ga Young Park; Yunho Lee; Dong-Heon Lee; Julia S. Woertink; Amy A. Narducci Sarjeant; Edward I. Solomon; Kenneth D. Karlin

doi:10.1039/B918616F

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Chemical Communications

Issue 1, 2010

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Thioether S-ligation in a side-on μ-η²:η²-peroxodicopper(II) complex

Ga Young Park , Yunho Lee , Dong-Heon Lee , Julia S. Woertink , Amy A. Narducci Sarjeant , Edward I. Solomon and Kenneth D. Karlin

Chem. Commun., 2010, 46, 91-93

DOI: 10.1039/B918616F
Received 08 Sep 2009, Accepted 14 Oct 2009
First published on the web 04 Nov 2009

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Abstract
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[(ANS)Cu^I(CH₃CN)]⁺ reacts with O₂ giving [{(ANS)Cu^II}₂(μ-η²:η²-O₂²⁻)]²⁺, ν_O–O = 731 cm⁻¹, shown to possess S-thioether ligation, based on comparisons with analogues having all N-ligands or a –S(Ph) group. The finding is a rare occurrence and new for side-on O₂²⁻ binding.

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Articles By

Ga Young Park
Yunho Lee
Dong-Heon Lee
Julia S. Woertink
Amy A. Narducci Sarjeant
Edward I. Solomon
Kenneth D. Karlin

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Chemical Communications

Thioether S-ligation in a side-on μ-η²:η²-peroxodicopper(II) complex

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