Formation of tetrameric water clusters driven by a cavitand template

Chiara Massera; Monica Melegari; Franco Ugozzoli; Enrico Dalcanale

doi:10.1039/B917931C

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Chemical Communications

Issue 1, 2010

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Formation of tetrameric water clusters driven by a cavitand template

Chiara Massera , Monica Melegari , Franco Ugozzoli and Enrico Dalcanale

Chem. Commun., 2010, 46, 88-90

DOI: 10.1039/B917931C
Received 02 Sep 2009, Accepted 08 Oct 2009
First published on the web 26 Oct 2009

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We describe an innovative approach to the generation of tetrameric water clusters in the solid state. The specific H-bond pattern induced by the tetraphosphonate cavitand template via its rigidly preorganized P [double bond, length as m-dash] O acceptor groups leads to the exclusive formation of the unique cyclic homodromic water tetramer of C₄ symmetry.

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Chemical Communications

Formation of tetrameric water clusters driven by a cavitand template

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