Hydrodeoxygenation of bio-derived phenols to hydrocarbons using RANEY® Ni and Nafion/SiO2 catalysts

Chen Zhao; Yuan Kou; Angeliki A. Lemonidou; Xuebing Li; Johannes A. Lercher

doi:10.1039/B916822B

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Chemical Communications

Issue 3, 2010

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Hydrodeoxygenation of bio-derived phenols to hydrocarbons using RANEY® Ni and Nafion/SiO₂ catalysts

Chen Zhao , Yuan Kou , Angeliki A. Lemonidou , Xuebing Li and Johannes A. Lercher

Chem. Commun., 2010, 46, 412-414

DOI: 10.1039/B916822B
Received 14 Aug 2009, Accepted 23 Oct 2009
First published on the web 18 Nov 2009

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Abstract
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A simple, green, cost- and energy-efficient route for converting phenolic components in bio-oil to hydrocarbons and methanol has been developed, with nearly 100% yields. In the heterogeneous catalysts, RANEY® Ni acts as the hydrogenation catalyst and Nafion/SiO₂ acts as the Brønsted solid acid for hydrolysis and dehydration.

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Supplementary Info

The GC-MS product spectrum, a photo of the hydrocarbonproduct after reactions, the proposed reaction pathways andphenolic monomer hydrodeoxygenation reactions
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Articles By

Chen Zhao
Yuan Kou
Angeliki A. Lemonidou
Xuebing Li
Johannes A. Lercher

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Chemical Communications

Hydrodeoxygenation of bio-derived phenols to hydrocarbons using RANEY® Ni and Nafion/SiO₂ catalysts

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