Subtleties in asymmetric catalyst structure: the resolution of a 6-phospha-2,4,8-trioxa-adamantane and its applications in asymmetric hydrogenation catalysis

Jonathan Hopewell; Piotr Jankowski; Claire L. McMullin; A. Guy Orpen; Paul G. Pringle

doi:10.1039/B916359J

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Chemical Communications

Issue 1, 2010

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Subtleties in asymmetric catalyst structure: the resolution of a 6-phospha-2,4,8-trioxa-adamantane and its applications in asymmetric hydrogenation catalysis

Jonathan Hopewell , Piotr Jankowski , Claire L. McMullin , A. Guy Orpen and Paul G. Pringle

Chem. Commun., 2010, 46, 100-102

DOI: 10.1039/B916359J
Received 11 Aug 2009, Accepted 08 Oct 2009
First published on the web 02 Nov 2009
This article is part of the collection: Selective Catalysis for Organic Synthesis

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An efficient, classical resolution of the versatile P-ligand intermediate 6-phospha-2,4,8-trioxa-adamantane (CgPH) is described and the rhodium complex of the optically pure secondary phosphine β-CgPH is an active and moderately selective asymmetric hydrogenation catalyst.

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Full experimental details for the synthesis andcharacterisation of the ligands and complexes, conditions used forthe catalysis and X-ray structural data
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Jonathan Hopewell
Piotr Jankowski
Claire L. McMullin
A. Guy Orpen
Paul G. Pringle

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Chemical Communications

Subtleties in asymmetric catalyst structure: the resolution of a 6-phospha-2,4,8-trioxa-adamantane and its applications in asymmetric hydrogenation catalysis

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