Metal–organic replica of chiral natural material β-SnF2: an enantiopure binodal (3,5)-connected net based on triangular and trigonal bipyramidal coordination

Jie Qin; Chao Qin; Xin-Long Wang; En-Bo Wang; Zhong-Min Su

doi:10.1039/B914582F

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Chemical Communications

Issue 4, 2010

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Metal–organic replica of chiral natural material β-SnF₂: an enantiopure binodal (3,5)-connected net based on triangular and trigonal bipyramidal coordination

Jie Qin , Chao Qin , Xin-Long Wang , En-Bo Wang and Zhong-Min Su

Chem. Commun., 2010, 46, 604-606

DOI: 10.1039/B914582F
Received 20 Jul 2009, Accepted 04 Nov 2009
First published on the web 19 Nov 2009

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Abstract
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A chiral (3,5)-connected metal–organic framework, based on triangular and trigonal bipyramidal coordiantion, exhibits an unprecedented β-SnF₂ topology, and represents the first heterocoordinated chiral metal–organic analogue presently known with a natural material topology.

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Supplementary Info

Mineral topologies that have been imitated in MOFs and Fig.S1–S3
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Crystal structure data
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Jie Qin
Chao Qin
Xin-Long Wang
En-Bo Wang
Zhong-Min Su

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Chemical Communications

Metal–organic replica of chiral natural material β-SnF₂: an enantiopure binodal (3,5)-connected net based on triangular and trigonal bipyramidal coordination

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