Self-association based on orthogonal COCO interactions in the solid and liquid state

Christoph Fäh; Leo A. Hardegger; Marc-Olivier Ebert; W. Bernd Schweizer; François Diederich

doi:10.1039/B912721F

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Chemical Communications

Issue 1, 2010

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Self-association based on orthogonal COCO interactions in the solid and liquid state

Christoph Fäh , Leo A. Hardegger , Marc-Olivier Ebert , W. Bernd Schweizer and François Diederich

Chem. Commun., 2010, 46, 67-69

DOI: 10.1039/B912721F
Received 29 Jun 2009, Accepted 26 Oct 2009
First published on the web 06 Nov 2009

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Abstract
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A network of orthogonal C [double bond, length as m-dash] OCO interactions was identified in the X-ray crystal structure of an α,α-difluorocyclopentanone derivative. This finding inspired investigations of self-association driven by these weak dipolar interactions in apolar solvents, which was proven by ¹H NMR spectroscopy.

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Crystallographic data of (±)-1, reference compounds, additional data on theself-association studies in solution
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Crystal structure data
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Articles By

Christoph Fäh
Leo A. Hardegger
Marc-Olivier Ebert
W. Bernd Schweizer
François Diederich

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Chemical Communications

Self-association based on orthogonal COCO interactions in the solid and liquid state

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