Unusual partner radical trimer formation in a host complex of cucurbit[8]uril, ruthenium(II) tris-bipyridine linked phenol and methyl viologen

Shiguo Sun; Samir Andersson; Rong Zhang; Licheng Sun

doi:10.1039/B910575A

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Chemical Communications

Issue 3, 2010

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Unusual partner radical trimer formation in a host complex of cucurbit[8]uril, ruthenium(II) tris-bipyridine linked phenol and methyl viologen

Shiguo Sun , Samir Andersson , Rong Zhang and Licheng Sun

Chem. Commun., 2010, 46, 463-465

DOI: 10.1039/B910575A
Received 29 May 2009, Accepted 23 Oct 2009
First published on the web 13 Nov 2009

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Abstract
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A stable 1 : 1 : 1 inclusion complex of Ru(bpy)₃-phenol (1), MV²⁺ and cucurbit[8]uril (CB[8]) is formed in aqueous solution. In the presence of triethanolamine (TEOA), a light-induced formation of unusual partner radical trimer 1–(MV⁺˙)₂–CB[8] has been observed for the first time.

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Chemical Communications

Unusual partner radical trimer formation in a host complex of cucurbit[8]uril, ruthenium(II) tris-bipyridine linked phenol and methyl viologen

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