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Issue 1, 2011
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Electrophilic functionalization of well-behaved manganese monoanions supported by m-terphenyl isocyanides

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Abstract

The m-terphenyl isocyanides CNArMes2 and CNArDipp2 support five-coordinate, isocyanide/carbonyl monoanions of manganese. For CNArDipp2, a bis-isocyanide anion is available that is remarkably well behaved upon reaction with electrophiles. Most notable is the formation of an unprecedented chloride-substituted metallostannylene.

Graphical abstract: Electrophilic functionalization of well-behaved manganese monoanions supported by m-terphenyl isocyanides

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Publication details

The article was received on 23 Jul 2010, accepted on 24 Aug 2010 and first published on 17 Sep 2010


Article type: Communication
DOI: 10.1039/C0CC02742A
Citation: Chem. Commun., 2011,47, 406-408
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    Electrophilic functionalization of well-behaved manganese monoanions supported by m-terphenyl isocyanides

    M. A. Stewart, C. E. Moore, T. B. Ditri, L. A. Labios, A. L. Rheingold and J. S. Figueroa, Chem. Commun., 2011, 47, 406
    DOI: 10.1039/C0CC02742A

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