Issue 32, 2010

Probing heterocycle conformation with residual dipolar couplings

Abstract

Residual dipolar couplings (RDCs) obtained in a stretched polydimethylsiloxane gel are applied to determine the 7-membered ring conformation in a 2-phenyl-3-benzazepine derivative, and to simultaneously assign all methylene proton pairs using only 1DCH RDCs and DFT molecular modelling data.

Graphical abstract: Probing heterocycle conformation with residual dipolar couplings

Supplementary files

Article information

Article type
Communication
Submitted
06 May 2010
Accepted
14 Jun 2010
First published
13 Jul 2010

Chem. Commun., 2010,46, 5879-5881

Probing heterocycle conformation with residual dipolar couplings

C. Gayathri, M. C. de la Fuente, B. Luy, R. R. Gil and A. Navarro-Vázquez, Chem. Commun., 2010, 46, 5879 DOI: 10.1039/C0CC01271H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements