Issue 29, 2010

Introduction of cavities up to 4 nm into a hierarchically-assembled metal–organic framework using an angular, tetratopic ligand

Abstract

Cavities up to 4 nm have been introduced into a hierarchically-assembled metal–organic framework by adopting an angular, semi-flexible tetratopic ligand. The resulting MOF possesses permanent porosity and exhibits stepwise sorption isotherms for O2 and N2 gases.

Graphical abstract: Introduction of cavities up to 4 nm into a hierarchically-assembled metal–organic framework using an angular, tetratopic ligand

Supplementary files

Article information

Article type
Communication
Submitted
05 Apr 2010
Accepted
28 May 2010
First published
23 Jun 2010

Chem. Commun., 2010,46, 5223-5225

Introduction of cavities up to 4 nm into a hierarchically-assembled metal–organic framework using an angular, tetratopic ligand

W. Zhuang, S. Ma, X. Wang, D. Yuan, J. Li, D. Zhao and H. Zhou, Chem. Commun., 2010, 46, 5223 DOI: 10.1039/C0CC00779J

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