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Issue 25, 2010
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Rational synthesis, enrichment, and 13C NMR spectra of endohedral C60 and C70 encapsulating a helium atom

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Abstract

Endohedral fullerenes encapsulating a helium atom, i.e., He@C60 and He@C70, at occupation levels of 30% were prepared by rational chemical synthesis. The existence of weak interactions between the inner helium and the outer fullerene cages was demonstrated by experimental and computational investigations.

Graphical abstract: Rational synthesis, enrichment, and 13C NMR spectra of endohedral C60 and C70 encapsulating a helium atom

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Publication details

The article was received on 25 Feb 2010, accepted on 12 Apr 2010 and first published on 12 May 2010


Article type: Communication
DOI: 10.1039/C0CC00113A
Citation: Chem. Commun., 2010,46, 4532-4534
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    Rational synthesis, enrichment, and 13C NMR spectra of endohedral C60 and C70 encapsulating a helium atom

    Y. Morinaka, F. Tanabe, M. Murata, Y. Murata and K. Komatsu, Chem. Commun., 2010, 46, 4532
    DOI: 10.1039/C0CC00113A

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