Issue 20, 2010
From the journal:

Chemical Communications

Nitroxidepolymer networks formed by Michael addition: on site-cured electrode-active organic coating†

Takeshi Ibe,a   Rainer B. Frings,b   Artur Lachowicz,b   Soichi Kyoa  and  Hiroyuki Nishide*a  

* Corresponding authors

a Department of Applied Chemistry, Waseda University, 169-8555 Tokyo, Japan
E-mail: nishide@waseda.jp
Fax: +81 (0)3 3209 5522
Tel: +81 (0)3 3200 2669

b DIC Berlin GmbH R&D Laboratory, 13403 Berlin, Germany
E-mail: lachowicz-a@dic-berlin.de
Fax: +49 (0)30 435 79 0 10
Tel: +49 (0)30 435 79 9 10

Abstract

Highly and homogeneously crosslinked poly(β-ketoester) networks densely bearing robust nitroxide radicals were prepared via a click-type and stepwise Michael polyaddition. A half-battery cell composed of the thermally-cured radical network coatings displayed a rapid, reversible, and almost stoichiometric redox-activity even with a thickness of ca. 10 μm, which may be applicable as the electrode of organic-based rechargeable devices.

Graphical abstract: Nitroxide polymer networks formed by Michael addition: on site-cured electrode-active organic coating

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Article information

DOI
https://doi.org/10.1039/C002797A
Article type
Communication
Submitted
09 Feb 2010
Accepted
13 Apr 2010
First published
23 Apr 2010

Chem. Commun., 2010,46, 3475-3477

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Nitroxide polymer networks formed by Michael addition: on site-cured electrode-active organic coating

T. Ibe, R. B. Frings, A. Lachowicz, S. Kyo and H. Nishide, Chem. Commun., 2010, 46, 3475 DOI: 10.1039/C002797A

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