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Issue 1, 2010
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Single and double substrate insertion into the Ti[double bond, length as m-dash]Nα bonds of terminal titanium hydrazides

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Abstract

Nitriles, CO2 and isocyanates undergo net single or double insertion reactions into the Ti[double bond, length as m-dash]Nα multiple bonds of terminal titanium hydrazides. These are the first such examples of this type of reactivity for any transition metal hydrazide complex.

Graphical abstract: Single and double substrate insertion into the Ti [[double bond, length as m-dash]] Nα bonds of terminal titanium hydrazides

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Publication details

The article was received on 28 Sep 2009, accepted on 02 Nov 2009 and first published on 19 Nov 2009


Article type: Communication
DOI: 10.1039/B920090H
Citation: Chem. Commun., 2010,46, 85-87
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    Single and double substrate insertion into the Ti[double bond, length as m-dash]Nα bonds of terminal titanium hydrazides

    P. Tiong, A. D. Schofield, J. D. Selby, A. Nova, E. Clot and P. Mountford, Chem. Commun., 2010, 46, 85
    DOI: 10.1039/B920090H

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