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Issue 7, 2010
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A mild, catalytic and efficient Nazarov cyclization mediated by phosphomolybdic acid

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Abstract

A mild, selective and efficient Nazarov cyclization of divinyl ketones catalyzed by phosphomolybdic acid (PMA) is described. The process demonstrates a broad substrate scope with functional group tolerance under short reaction times. PMA supported on silica gel is more efficient than the bulk catalyst and is recycled up to three times without significant activity loss.

Graphical abstract: A mild, catalytic and efficient Nazarov cyclization mediated by phosphomolybdic acid

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Publication details

The article was received on 04 Sep 2009, accepted on 04 Dec 2009 and first published on 24 Dec 2009


Article type: Communication
DOI: 10.1039/B918137G
Citation: Chem. Commun., 2010,46, 1127-1129
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    A mild, catalytic and efficient Nazarov cyclization mediated by phosphomolybdic acid

    K. Murugan, S. Srimurugan and C. Chen, Chem. Commun., 2010, 46, 1127
    DOI: 10.1039/B918137G

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