Reaction mechanisms

Dean J. Tantillo; Jeehiun K. Lee

doi:10.1039/B822065B

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Annual Reports Section "B" (Organic Chemistry)

Issue 0, 2009

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Reaction mechanisms
Part (ii) Pericyclic reactions

Dean J. Tantillo and Jeehiun K. Lee

Annu. Rep. Prog. Chem., Sect. B: Org. Chem., 2009, 105, 285-309

DOI: 10.1039/B822065B
First published on the web 02 Jun 2009

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Abstract
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This report surveys the 2008 literature on mechanisms of pericyclic reactions. A recurring theme in this year’s reports is again catalysis. Several studies addressed the acceleration of pericyclic reactions by electron transfer, protonation, encapsulation-induced preorganization and selective transition state stabilization via hydrogen bonding or Lewis acid complexation. In addition, the mechanisms of a variety of pericyclic reactions leading to interesting polycycles were examined in detail, and several cases of theoretical predictions being verified experimentally were described.

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Annual Reports Section "B" (Organic Chemistry)

Reaction mechanisms
Part (ii) Pericyclic reactions

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Annual Reports Section "B" (Organic Chemistry)

Reaction mechanismsPart (ii) Pericyclic reactions

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Reaction mechanisms
Part (ii) Pericyclic reactions