Magnesium-mediated intramolecular reductive coupling: a stereoselective synthesis of C2-symmetric 3,4-bis-silyl-substituted adipic acid derivatives

Pintu K. Kundu; Sunil K. Ghosh

doi:10.1039/B910784C

skip RSC | ChemSpider | Feedback

Home > Journals > Organic & Biomolecular ... > Magnesium-mediated intr...

Authors & Referees | Librarians

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Organic & Biomolecular Chemistry

Issue 22, 2009

More about this Journal
Editorial Board
Submit an Article

Follow Journal | |

Journal Home | RSC Journals

Paper

Previous Article | Next Article

Magnesium-mediated intramolecular reductive coupling: a stereoselective synthesis of C₂-symmetric 3,4-bis-silyl-substituted adipic acid derivatives

Pintu K. Kundu and Sunil K. Ghosh

Org. Biomol. Chem., 2009, 7, 4611-4621

DOI: 10.1039/B910784C
Received 02 Jun 2009, Accepted 07 Aug 2009
First published on the web 14 Sep 2009

Please wait while Download options loads

Request Permissions

Abstract
Cited by
Compounds
Related Content

Chiral C₂-symmetric 3,4-bis-silyl-substituted adipic acid derivatives have been synthesised by a Mg/trimethylsilyl chloride-mediated intramolecular reductive coupling of symmetrical disiloxanes of β-silylacrylic acid N-oxazolidinone derivatives. Efficient and short syntheses of enantiomerically pure enantiomers of 2,6-dioxabicyclo[3.3.0]octane-3,7-dione have been achieved from the bis-silylated adipic acid derivatives using Fleming–Tamao oxidation as the key step.

This may take some time to load.

Supplementary Info

Copies of ¹H and ¹³C spectra of new compounds
PDF (1648K)

Terms & Conditions|Privacy |Accessibility|ACAP Enabled

Organic & Biomolecular Chemistry

Magnesium-mediated intramolecular reductive coupling: a stereoselective synthesis of C₂-symmetric 3,4-bis-silyl-substituted adipic acid derivatives

Log in (Free Access)

Log in (Subscriber Access)

Supplementary Info

Articles By