Ionic liquid: an efficient and recyclable medium for synthesis of unsymmetrical diorganyl selenides promoted by InI

Senthil Narayanaperumal; Eduardo E. Alberto; Fabiano Molinos de Andrade; Eder J. Lenardão; Paulo S. Taube; Antonio L. Braga

doi:10.1039/B910699E

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Organic & Biomolecular Chemistry

Issue 22, 2009

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Ionic liquid: an efficient and recyclable medium for synthesis of unsymmetrical diorganyl selenides promoted by InI

Senthil Narayanaperumal , Eduardo E. Alberto , Fabiano Molinos de Andrade , Eder J. Lenardão , Paulo S. Taube and Antonio L. Braga

Org. Biomol. Chem., 2009, 7, 4647-4650

DOI: 10.1039/B910699E
Received 02 Jun 2009, Accepted 03 Aug 2009
First published on the web 08 Sep 2009

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Abstract
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In an environmentally friendly protocol, InI was used as a reducing agent for the Se–Se bond to prepare unsymmetrical diorganyl selenides with very short reaction times, mild conditions and excellent yields using (bmim)BF₄ as a recyclable solvent.

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¹H and ¹³C NMR spectra of all compounds
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Articles By

Senthil Narayanaperumal
Eduardo E. Alberto
Fabiano Molinos de Andrade
Eder J. Lenardão
Paulo S. Taube
Antonio L. Braga

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Organic & Biomolecular Chemistry

Ionic liquid: an efficient and recyclable medium for synthesis of unsymmetrical diorganyl selenides promoted by InI

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