Ni and Pd mediate asymmetric organoboron synthesis with ester functionality at the β-position

Vanesa Lillo; Michael J. Geier; Stephen A. Westcott; Elena Fernández

doi:10.1039/B909341A

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Organic & Biomolecular Chemistry

Issue 22, 2009

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Ni and Pd mediate asymmetric organoboron synthesis with ester functionality at the β-position

Vanesa Lillo , Michael J. Geier , Stephen A. Westcott and Elena Fernández

Org. Biomol. Chem., 2009, 7, 4674-4676

DOI: 10.1039/B909341A
Received 11 May 2009, Accepted 27 Jul 2009
First published on the web 03 Sep 2009

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Catalytic systems based on Ni and Pd complexes modified with chiral P-P ligands can be used in a convenient strategy for enantioselectively adding a boron unit to the β-position of α,β-unsaturated esters.

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Experimental procedure for the metal-catalyzed asymmetricβ-boration of α,β-unsaturated esters withbis(pinacolato)diboron; characterization data for compounds
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Organic & Biomolecular Chemistry

Ni and Pd mediate asymmetric organoboron synthesis with ester functionality at the β-position

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