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Issue 13, 2009
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Mechanistic insight into TEMPO-inhibited polymerisation: simultaneous determination of oxygen and inhibitor concentrations by EPR

Marco Conte,a  Yun Ma,a  Colin Loyns,b  Peter Price,b  David Ripponb  and  Victor Chechik*a 
Author affiliations

* Corresponding authors

a Department of Chemistry, University of York, Heslington, UK
E-mail: vc4@york.ac.uk

b Nufarm Limited, Wyke Lane, Wyke, UK

Abstract

Convolution-based fitting of EPR spectra makes it possible to simultaneously determine concentrations of TEMPO and oxygen in TEMPO-inhibited polymerisations and autoxidations; this method is useful for understanding the chemistry of inhibitor mixtures.

Graphical abstract: Mechanistic insight into TEMPO-inhibited polymerisation: simultaneous determination of oxygen and inhibitor concentrations by EPR

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Publication details

The article was received on 25 Mar 2009, accepted on 12 May 2009 and first published on 26 May 2009


Article type: Communication
DOI: 10.1039/B905893A
Citation: Org. Biomol. Chem., 2009,7, 2685-2687
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    Mechanistic insight into TEMPO-inhibited polymerisation: simultaneous determination of oxygen and inhibitor concentrations by EPR

    M. Conte, Y. Ma, C. Loyns, P. Price, D. Rippon and V. Chechik, Org. Biomol. Chem., 2009, 7, 2685
    DOI: 10.1039/B905893A

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