New haliclamines E and F from the Arctic sponge Haliclona viscosa

Gesine Schmidt; Christoph Timm; Matthias Köck

doi:10.1039/B904157E

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Organic & Biomolecular Chemistry

Issue 15, 2009

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New haliclamines E and F from the Arctic sponge Haliclona viscosa

Gesine Schmidt , Christoph Timm and Matthias Köck

Org. Biomol. Chem., 2009, 7, 3061-3064

DOI: 10.1039/B904157E
Received 27 Feb 2009, Accepted 13 May 2009
First published on the web 18 Jun 2009

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The Arctic sponge Haliclona viscosa is a rich source of 3-alkyl pyridinium alkaloids. Herein, we report the identification of two new haliclamines from the crude extract of this sponge. Due to the lack of sponge material, identification relied on HR-LCMS measurements and comparison with synthetic compounds.

Abstract from Natural Product Updates 2009

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Supplementary Info

MS spectra of the natural and the synthetic haliclamines; NMRspectra and shifts of the synthetic haliclamines; synthetic pathwayof compounds 1–4
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Organic & Biomolecular Chemistry

New haliclamines E and F from the Arctic sponge Haliclona viscosa

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