Organocatalyzed direct asymmetric α-halogenation of carbonyl compounds

Mitsuhiro Ueda; Taichi Kano; Keiji Maruoka

doi:10.1039/B901449G

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Organic & Biomolecular Chemistry

Issue 10, 2009

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Organocatalyzed direct asymmetric α-halogenation of carbonyl compounds

Mitsuhiro Ueda , Taichi Kano and Keiji Maruoka

Org. Biomol. Chem., 2009, 7, 2005-2012

DOI: 10.1039/B901449G
Received 22 Jan 2009, Accepted 16 Feb 2009
First published on the web 19 Mar 2009

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The formation of carbon–halogen bonds in an enantioselective manner is an important reaction because it leads to optically active halogen compounds, which are useful intermediates for further elaboration to other valuable compounds. Within the past few years various enantioselective α-halogenations of carbonyl compounds by asymmetric organocatalysis have been reported. Most importantly, these recent developments have greatly enhanced the synthetic utility of α-halogenations and opened up a promising new frontier in organic synthesis.

Abstract from Methods in Organic Synthesis 2009

A review, with 22 references, covering recent advances in the field of organocatalysed asymmetric α-halogenation reactions of carbonyl compounds.

Abstract from Catalysts & Catalysed Reactions 2009

A review, with 22 references, of recent advances in the field of organocatalysed asymmetric α-halogenation reactions of carbonyl compounds.

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Organocatalyzed direct asymmetric α-halogenation of carbonyl compounds

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