π-Activated alcohols: an emerging class of alkylating agents for catalytic Friedel–Crafts reactions

Marco Bandini; Michele Tragni

doi:10.1039/B823217B

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Organic & Biomolecular Chemistry

Issue 8, 2009

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π-Activated alcohols: an emerging class of alkylating agents for catalytic Friedel–Crafts reactions

Marco Bandini and Michele Tragni

Org. Biomol. Chem., 2009, 7, 1501-1507

DOI: 10.1039/B823217B
Received 05 Jan 2009, Accepted 23 Jan 2009
First published on the web 02 Mar 2009

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Abstract
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The direct functionalization of aromatic compounds, via Friedel–Crafts alkylation reactions with alcohols, is one of the cornerstones in organic chemistry. The present emerging area deals with the recent advances in the use of π-activated alcohols in the catalytic and stereoselective construction of benzylic stereocenters.

Abstract from Methods in Organic Synthesis 2009

A review, with 28 references, discussing recent advances in the use of π-activated alcohols in Friedel–Crafts alkylation reactions to construct benzylic stereocentres.

Abstract from Catalysts & Catalysed Reactions 2009

A review, with 28 references, discussing the construction of benzylic stereocentres from π-activated alcohols.

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Organic & Biomolecular Chemistry

π-Activated alcohols: an emerging class of alkylating agents for catalytic Friedel–Crafts reactions

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