Design and synthesis of phosphole-based π systems for novel organic materials

Yoshihiro Matano; Hiroshi Imahori

doi:10.1039/B819255N

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Organic & Biomolecular Chemistry

Issue 7, 2009

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Design and synthesis of phosphole-based π systems for novel organic materials

Yoshihiro Matano and Hiroshi Imahori

Org. Biomol. Chem., 2009, 7, 1258-1271

DOI: 10.1039/B819255N
Received 29 Oct 2008, First published on the web 27 Jan 2009

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Phospholes are known to exhibit characteristic optical and electrochemical properties derived from the phosphorus-bridged 1,3-dienic π system. Particular interest has recently been paid to their π-conjugated derivatives, such as non-fused phospholes, dibenzo[b,d]phospholes, benzo[b]phospholes, benzo[c]phospholes and related compounds. This perspective focuses on recent advances in the synthesis of these phosphole-based π systems with representative examples that would give valuable guidelines for designing phosphole-containing opto-electrochemical materials.

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Organic & Biomolecular Chemistry

Design and synthesis of phosphole-based π systems for novel organic materials

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