Metal-catalysed halogen exchange reactions of aryl halides

Tom D. Sheppard

doi:10.1039/B818155A

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Organic & Biomolecular Chemistry

Issue 6, 2009

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Metal-catalysed halogen exchange reactions of aryl halides

Tom D. Sheppard

Org. Biomol. Chem., 2009, 7, 1043-1052

DOI: 10.1039/B818155A
Received 15 Oct 2008, Accepted 11 Dec 2008
First published on the web 30 Jan 2009

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Aryl halides are common synthetic targets themselves, and also highly versatile synthetic intermediates. Aryl chlorides are much more widely available and easier to synthesise than the other halide derivatives, so the development of effective methods for interconverting aryl halide derivatives would therefore be extremely useful. This article outlines which transformations are particularly desirable, and describes the progress that has been made on developing methods for carrying out those transformations using copper, nickel or palladium catalysts. The possible mechanisms of these reactions are discussed, with a view to identifying areas for future investigation.

Abstract from Methods in Organic Synthesis 2009

A review, with 63 references, describing the progress that has been made in developing methods for desirable aryl halide interconversions using copper, nickel or palladium catalysts.

Abstract from Catalysts & Catalysed Reactions 2009

A review, with 63 references, describing the progress that has been made in developing methods for desirable aryl halide interconversions using copper, nickel or palladium catalysts.

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Organic & Biomolecular Chemistry

Metal-catalysed halogen exchange reactions of aryl halides

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