Jump to main content
Jump to site search

Issue 11, 2009
Previous Article Next Article

Radical pairs with rotational fluidity in the photochemical reaction of acetophenone and cyclohexane in the zeolite NAY: a 13C CPMAS NMR and product analysis study

Author affiliations

Abstract

The photochemical reaction of acetophenone and cyclohexane in the zeolite NaY occurs by combination of the geminate radical pairs to give products that reveal a significant amount of rotational fluidity, which was also documented by intermolecular nuclear dipolar interaction measurements using cross polarization 13C NMR (CPMAS) experiments.

Graphical abstract: Radical pairs with rotational fluidity in the photochemical reaction of acetophenone and cyclohexane in the zeolite NAY: a 13C CPMAS NMR and product analysis study

Back to tab navigation

Publication details

The article was received on 02 Sep 2008, accepted on 17 Feb 2009 and first published on 16 Apr 2009


Article type: Paper
DOI: 10.1039/B815266G
Citation: Org. Biomol. Chem., 2009,7, 2322-2326
  •   Request permissions

    Radical pairs with rotational fluidity in the photochemical reaction of acetophenone and cyclohexane in the zeolite NAY: a 13C CPMAS NMR and product analysis study

    A. Amboya, T. Nguyen, H. T. Huynh, A. Brown, G. Ratliff, H. Yonutas, D. Cizmeciyan, A. Natarajan and M. A. Garcia Garibay, Org. Biomol. Chem., 2009, 7, 2322
    DOI: 10.1039/B815266G

Search articles by author

Spotlight

Advertisements