Does mesoporosity enhance thin film properties? A question of electrode material for electrochromism of WO3

Rainer Ostermann; Bernd Smarsly

doi:10.1039/B9NR00091G

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Nanoscale

Issue 2, 2009

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Does mesoporosity enhance thin film properties? A question of electrode material for electrochromism of WO₃

Rainer Ostermann and Bernd Smarsly

Nanoscale, 2009, 1, 266-270

DOI: 10.1039/B9NR00091G
Received 29 May 2009, Accepted 10 Aug 2009
First published on the web 28 Aug 2009

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Replacing the commonly used indium tin oxide (ITO) with a thin metal layer as a quasi-transparent electrode leads to enhancement and acceleration of the electrochromic response of WO₃, as otherwise there is an electronic activation barrier at the interface between WO₃ and the ITO electrode, impeding fast electron transfer.

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Comparison of the variation of absorbance and charge inserted/extracted for WO ₃ films on gold and ITO. Electrochromic response of WO ₃ films of different thickness
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Nanoscale

Does mesoporosity enhance thin film properties? A question of electrode material for electrochromism of WO₃

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