Supramolecular self-organization in constitutional hybrid materials†
Abstract
We present in this paper a new strategy to transcribe the supramolecular dynamic self-organization of the G-quadruplex and ureidocrown ether ion channel-type columnar architectures in constitutional hybrids. In particular, the use of a “dynamic reversible hydrophobic interface” can render the emerging hybrid mesophases self-adaptive. The reversible hydrophobic interactions allow both supramolecular and inorganic