N-Heterocyclic carbene coated metal nanoparticles

Eleanor C. Hurst; Karen Wilson; Ian J. S. Fairlamb; Victor Chechik

doi:10.1039/B905559B

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New Journal of Chemistry

Issue 9, 2009

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N-Heterocyclic carbene coated metal nanoparticles

Eleanor C. Hurst , Karen Wilson , Ian J. S. Fairlamb and Victor Chechik

New J. Chem., 2009, 33, 1837-1840

DOI: 10.1039/B905559B
Received 20 Mar 2009, Accepted 16 Jul 2009
First published on the web 30 Jul 2009

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Abstract
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N-Heterocyclic carbene coated Au and Pd nanoparticles have been prepared by a ligand exchange reaction; although carbenes quantitatively displaced the thioether and phosphine ligands from the nanoparticle surface, the resultant nanoparticles spontaneously leached metal complexes and aggregated in solution.

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