Issue 5, 2009
From the journal:

New Journal of Chemistry

Carbonylative 1,4-addition of potassium aryltrifluoroborates to vinyl ketones†

Mathieu Sauthier,*a   Nicolas Lamotte,a   Julien Dheur,a   Yves Castaneta  and  André Mortreuxa  

* Corresponding authors

a Unité de Catalyse et Chimie du Solide, UMR CNRS 8181–USTL, ENSCL, BP 90108, Villeneuve d’Ascq, France
E-mail: mathieu.sauthier@univ-lille1.fr
Fax: +33 (0)3 20 43 65 85

Abstract

Potassium aryltrifluoroborates have proven to be useful reagents for the carbonylative aroylation of vinyl ketones; this study broadens the scope of potassium aryltrifluoroborates in homogeneous catalysis and shows that the solvent can act as the proton source for this family of reactions.

Graphical abstract: Carbonylative 1,4-addition of potassium aryltrifluoroborates to vinyl ketones

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Article information

DOI
https://doi.org/10.1039/B900361D
Article type
Letter
Submitted
09 Jan 2009
Accepted
19 Feb 2009
First published
20 Mar 2009

New J. Chem., 2009,33, 969-971

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Carbonylative 1,4-addition of potassium aryltrifluoroborates to vinyl ketones

M. Sauthier, N. Lamotte, J. Dheur, Y. Castanet and A. Mortreux, New J. Chem., 2009, 33, 969 DOI: 10.1039/B900361D

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