Issue 2, 2009
From the journal:

New Journal of Chemistry

Construction of hexanuclear macrocycles by a coupling strategy from polyfunctionalized bis(terpyridines)†‡

Ibrahim Eryazicia  and  George R. Newkome*ab  

* Corresponding authors

a Department of Polymer Science, The University of Akron, Akron, USA

b Department of Chemistry, The University of Akron, Akron, USA
E-mail: newkome@uakron.edu
Web: http://www.dendrimers.com
Fax: +1 330 972 2413
Tel: +1 330 972 6458

Abstract

The construction of a heteronuclear (Ru4Fe2) hexameric metallomacrocycle with methyl- and carbonyl-functionalized bis(terpyridyl) moieties was achieved by a self-assembly of a dinuclear trimer, which was prepared in high yield viaPd(0) coupling of a bis-iodo functionalized dinuclear complex with a terpyridine possessing an acetylene group.

Graphical abstract: Construction of hexanuclear macrocycles by a coupling strategy from polyfunctionalized bis(terpyridines)

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Article information

DOI
https://doi.org/10.1039/B811607E
Article type
Paper
Submitted
09 Jul 2008
Accepted
26 Sep 2008
First published
05 Dec 2008

New J. Chem., 2009,33, 345-357

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Construction of hexanuclear macrocycles by a coupling strategy from polyfunctionalized bis(terpyridines)

I. Eryazici and G. R. Newkome, New J. Chem., 2009, 33, 345 DOI: 10.1039/B811607E

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