Issue 10, 2009
From the journal:

New Journal of Chemistry

The intramolecular C–F⋯HO hydrogen bond of 2-fluorophenyldiphenylmethanol†

Hiroyuki Takemura,*a   Megumi Kaneko,a   Katsuya Sakob  and  Tetsuo Iwanagac  

* Corresponding authors

a Department of Chemical and Biological Science, Faculty of Science, Japan Women’s University, Mejirodai 2-8-1, Bunkyou-ku, Japan

b Nagoya Institute of Technology, Department of Systems Management and Engineering, Gokiso, Showa-ku, Japan

c Department of Chemistry, Faculty of Science, Okayama University of Science, 1-1 Ridaicho, Japan

Abstract

The intramolecular C–F⋯HO hydrogen bond of 2-fluorophenyldiphenylmethanol was observed by X-ray crystallographic analysis and NMR spectroscopy. The features of the spectra were compared to triphenylmethanol (a fluorine-free analog) and 2-fluorophenyldiphenylmethane.

Graphical abstract: The intramolecular C–F⋯HO hydrogen bond of 2-fluorophenyldiphenylmethanol

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Article information

DOI
https://doi.org/10.1039/B902203A
Article type
Letter
Submitted
03 Feb 2009
Accepted
25 Aug 2009
First published
07 Sep 2009

New J. Chem., 2009,33, 2004-2006

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The intramolecular C–F⋯HO hydrogen bond of 2-fluorophenyldiphenylmethanol

H. Takemura, M. Kaneko, K. Sako and T. Iwanaga, New J. Chem., 2009, 33, 2004 DOI: 10.1039/B902203A

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