Issue 4, 2009
From the journal:

New Journal of Chemistry

Electropolymerization of triphenylamine–dithiafulvene hybrid extended pi-conjugated systems†

Nicolas Cocherel,a   Philippe Leriche,*a   Emilie Ripaud,a   Nuria Gallego-Planas,a   Pierre Frèrea  and  Jean Roncalia  

* Corresponding authors

a Department of Chemistry, Université d’Angers, CNRS, CIMA, 2 Boulevard Lavoisier, Angers, France
E-mail: Philippe.leriche@univ-angers.fr

Abstract

Extended hybrid conjugated systems based on a triphenylamine core with 1, 2 and 3 peripheral dithiafulvenyl units have been studied by cyclic voltammetry and UV-Vis absorption spectroscopy. The substitution pattern of the triphenylamine core determines two different electrochemical coupling mechanisms leading to two types of electrogenerated extended conjugated electroactive systems. The structure and properties of polymeric species are also presented.

Graphical abstract: Electropolymerization of triphenylamine–dithiafulvene hybrid extended pi-conjugated systems

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Article information

DOI
https://doi.org/10.1039/B819675C
Article type
Paper
Submitted
04 Nov 2008
Accepted
17 Dec 2008
First published
22 Jan 2009

New J. Chem., 2009,33, 801-806

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Electropolymerization of triphenylamine–dithiafulvene hybrid extended pi-conjugated systems

N. Cocherel, P. Leriche, E. Ripaud, N. Gallego-Planas, P. Frère and J. Roncali, New J. Chem., 2009, 33, 801 DOI: 10.1039/B819675C

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