How stable are 1,2-dihydro-1,2-azaborines toward water and oxygen?

Ashley N. Lamm; Shih-Yuan Liu

doi:10.1039/B904120F

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Molecular BioSystems

Issue 11, 2009

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How stable are 1,2-dihydro-1,2-azaborines toward water and oxygen?

Ashley N. Lamm and Shih-Yuan Liu

Mol. BioSyst., 2009, 5, 1303-1305

DOI: 10.1039/B904120F
Received 27 Feb 2009, Accepted 20 Jul 2009
First published on the web 10 Aug 2009

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The stability of 1,2-dihydro-1,2-azaborines toward oxygen and water was investigated as a function of their ring substituents: while generally 1,2-dihydro-1,2-azaborines are compatible with water, their stability toward oxygen is dependent on the boron and the C(3) substituents, and we found that electron withdrawing groups enhanced the heterocycle’s ability to resist oxidative degradation.

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Molecular BioSystems

How stable are 1,2-dihydro-1,2-azaborines toward water and oxygen?

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