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Issue 25, 2009
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Enhanced H2 adsorption enthalpy in the low-surface area, partially fluorinated coordination polymer Zn5(triazole)6(tetrafluoroterephthalate)2(H2O)2·4H2O

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Abstract

A porous coordination polymer containing zinc, 1,2,4-triazolate, and tetrafluoroterephthalate displays a high physisorptive hydrogen adsorption enthalpy of 8 kJ/mol, as a result of fluorine atoms exposed to the pore surface and the structure's small pore size.

Graphical abstract: Enhanced H2 adsorption enthalpy in the low-surface area, partially fluorinated coordination polymer Zn5(triazole)6(tetrafluoroterephthalate)2(H2O)2·4H2O

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Publication details

The article was received on 15 Jan 2009, accepted on 09 Mar 2009 and first published on 19 Mar 2009


Article type: Communication
DOI: 10.1039/B900879A
Citation: J. Mater. Chem., 2009,19, 4307-4309
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    Enhanced H2 adsorption enthalpy in the low-surface area, partially fluorinated coordination polymer Zn5(triazole)6(tetrafluoroterephthalate)2(H2O)2·4H2O

    Z. Hulvey, E. H. L. Falcao, J. Eckert and A. K. Cheetham, J. Mater. Chem., 2009, 19, 4307
    DOI: 10.1039/B900879A

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