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Issue 2, 2009
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Fabrication of photochemical pattern on a self-assembled monolayer (SAM) of a ruthenium cluster under electrochemical control

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Abstract

A new strategy is proposed for the fabrication of photochemical pattern of a self-assembled monolayer (SAM) of an oxo-centered tri-ruthenium (Ru3) cluster on a gold electrode surface. The fabrication was achieved under combined photochemical and electrochemical controls. By this strategy, the patterned SAM surfaces terminated with different kinds of moiety groups such as carbon monoxide (CO), nitric oxide (NO) and a successive layer of Ru3 cluster by ligand-exchange reaction are obtained with high yields.

Graphical abstract: Fabrication of photochemical pattern on a self-assembled monolayer (SAM) of a ruthenium cluster under electrochemical control

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Publication details

The article was received on 05 Sep 2008, accepted on 09 Oct 2008 and first published on 14 Nov 2008


Article type: Paper
DOI: 10.1039/B815571B
Citation: J. Mater. Chem., 2009,19, 261-267
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    Fabrication of photochemical pattern on a self-assembled monolayer (SAM) of a ruthenium cluster under electrochemical control

    Y. Zhang, Y. Tong, M. Abe, K. Uosaki, M. Osawa, Y. Sasaki and S. Ye, J. Mater. Chem., 2009, 19, 261
    DOI: 10.1039/B815571B

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