Selective production of cyclic carbonate over polycarbonate using a double metal cyanide–quaternary ammonium salt catalyst system

Manju Mamparambath Dharman; Jeong-In Yu; Ji-Yeon Ahn; Dae-Won Park

doi:10.1039/B916875N

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Green Chemistry

Issue 11, 2009

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Selective production of cyclic carbonate over polycarbonate using a double metal cyanide–quaternary ammonium salt catalyst system

Manju Mamparambath Dharman , Jeong-In Yu , Ji-Yeon Ahn and Dae-Won Park

Green Chem., 2009, 11, 1754-1757

DOI: 10.1039/B916875N
Received 25 May 2009, Accepted 17 Aug 2009
First published on the web 11 Sep 2009

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A double metal cyanide complex, an efficient catalyst for the copolymerization of CO₂ with epoxide, was successfully utilized for the cycloaddition of CO₂ to various epoxides in the presence of quaternary ammonium salts without any solvents.

Abstract from Methods in Organic Synthesis 2010

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Selective production of cyclic carbonate over polycarbonate using a double metal cyanide–quaternary ammonium salt catalyst system

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