Water as the medium of choice for the 1,3-dipolar cycloaddition reactions of hydrophobic nitrones

Evdoxia Coutouli-Argyropoulou; Prodromos Sarridis; Petros Gkizis

doi:10.1039/B916765J

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Green Chemistry

Issue 11, 2009

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Water as the medium of choice for the 1,3-dipolar cycloaddition reactions of hydrophobic nitrones

Evdoxia Coutouli-Argyropoulou , Prodromos Sarridis and Petros Gkizis

Green Chem., 2009, 11, 1906-1914

DOI: 10.1039/B916765J
Received 27 May 2009, Accepted 10 Aug 2009
First published on the web 17 Sep 2009

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Abstract
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1,3-Dipolar cycloadditions of different hydrophobic nitrones 1, 2, 3, 4 with acrylates 5 and 6 were studied in both homogenous organic solutions and aqueous suspensions. Reactions in water suspensions showed great rate accelerations over homogenous solutions. Small changes were also observed to the stereoselectivities of the reactions. Hydrophobic interactions are invoked for the observed behaviour.

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Green Chemistry

Water as the medium of choice for the 1,3-dipolar cycloaddition reactions of hydrophobic nitrones

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