Eco-friendly cross-coupling of diaryl diselenides with aryl and alkyl bromides catalyzed by CuO nanopowder in ionic liquid

Devender Singh; Eduardo E. Alberto; Oscar Endrigo Dorneles Rodrigues; Antonio Luiz Braga

doi:10.1039/B916266F

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Green Chemistry

Issue 10, 2009

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Eco-friendly cross-coupling of diaryl diselenides with aryl and alkyl bromides catalyzed by CuO nanopowder in ionic liquid

Devender Singh , Eduardo E. Alberto , Oscar Endrigo Dorneles Rodrigues and Antonio Luiz Braga

Green Chem., 2009, 11, 1521-1524

DOI: 10.1039/B916266F
Received 25 May 2009, Accepted 05 Aug 2009
First published on the web 17 Aug 2009

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An eco-friendly cross-coupling reaction of aryl and alkyl bromides with diselenides using a catalytic amount of CuO nanopowder as a catalyst and an ionic liquid as a recyclable solvent is reported. The system shows high efficiency to catalyze this transformation, and in a green fashion due to the recyclable approach and the non-residual design protocol. This procedure has been utilized for the synthesis of a variety of diaryl selenides in good to excellent yields from the readily available aryl and alkyl bromides and diselenides.

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Green Chemistry

Eco-friendly cross-coupling of diaryl diselenides with aryl and alkyl bromides catalyzed by CuO nanopowder in ionic liquid

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