Glycerol as a promoting medium for electrophilic activation of aldehydes: catalyst-free synthesis of di(indolyl)methanes, xanthene-1,8(2H)-diones and 1-oxo-hexahydroxanthenes

Fei He; Peng Li; Yanlong Gu; Guangxing Li

doi:10.1039/B916015A

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Green Chemistry

Issue 11, 2009

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Glycerol as a promoting medium for electrophilic activation of aldehydes: catalyst-free synthesis of di(indolyl)methanes, xanthene-1,8(2H)-diones and 1-oxo-hexahydroxanthenes

Fei He , Peng Li , Yanlong Gu and Guangxing Li

Green Chem., 2009, 11, 1767-1773

DOI: 10.1039/B916015A
Received 17 Jul 2009, Accepted 04 Aug 2009
First published on the web 07 Sep 2009

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Glycerol was used, for the first time, as a green and effective promoting medium for electrophilic activation of aldehydes, and with which, a catalyst-free system for some reactions that conventionally carried out using acid catalysts, such as synthesis of di(indolyl)methanes, 3,4,5,6,7,9-hexahydro-9-aryl-1H-xanthene-1,8(2H)-dione and 1-oxo-hexahydroxanthenes, was developed.

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Green Chemistry

Glycerol as a promoting medium for electrophilic activation of aldehydes: catalyst-free synthesis of di(indolyl)methanes, xanthene-1,8(2H)-diones and 1-oxo-hexahydroxanthenes

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