Selective transfer hydrogenolysis of glycerol promoted by palladium catalysts in absence of hydrogen

Maria Grazia Musolino; Luciano Antonio Scarpino; Francesco Mauriello; Rosario Pietropaolo

doi:10.1039/B915745J

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Green Chemistry

Issue 10, 2009

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Selective transfer hydrogenolysis of glycerol promoted by palladium catalysts in absence of hydrogen

Maria Grazia Musolino , Luciano Antonio Scarpino , Francesco Mauriello and Rosario Pietropaolo

Green Chem., 2009, 11, 1511-1513

DOI: 10.1039/B915745J
Received 04 Jun 2009, Accepted 31 Jul 2009
First published on the web 11 Aug 2009

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Selective conversion of glycerol into 1,2-propanediol in the presence of a Pd/Fe₂O₃ catalyst, under inert atmosphere, is reported for the first time; the hydrogen necessary for the hydrogenolysis reaction derives from the dehydrogenation of the solvent (2-propanol or ethanol), promoted by supported palladium, itself reduced “in situ” by alcohols.

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Green Chemistry

Selective transfer hydrogenolysis of glycerol promoted by palladium catalysts in absence of hydrogen

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