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Issue 11, 2009
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Strategies for cleaner oxidations using photochemically generated singlet oxygen in supercritical carbon dioxide

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Abstract

Photochemically generated singlet oxygen, 1O2, has been reacted with four different substrates in supercritical carbon dioxide. By using fluorous surfactants and a co-solvent to solubilise more polar photosensitisers and reactants respectively, the applicability of the system is greatly enhanced.

Graphical abstract: Strategies for cleaner oxidations using photochemically generated singlet oxygen in supercritical carbon dioxide

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Publication details

The article was received on 14 Jul 2009, accepted on 12 Aug 2009 and first published on 07 Sep 2009


Article type: Paper
DOI: 10.1039/B914074C
Citation: Green Chem., 2009,11, 1787-1792
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    Strategies for cleaner oxidations using photochemically generated singlet oxygen in supercritical carbon dioxide

    X. Han, R. A. Bourne, M. Poliakoff and M. W. George, Green Chem., 2009, 11, 1787
    DOI: 10.1039/B914074C

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